Examining Thermal and Salinity Impact on Flow of Crude Oil through Porous Media for Enhancing Recovery
Keywords:
Low salinity, Oil recovery, Reservoir temperature, Water flooding, Wettability alterationAbstract
The objective of this study is to examine the influence of reservoir temperature and injected formation brine salinity on oil recovery enhancement in brown oil fields. The study employed core flooding experiments using actual crude oil-producing porous media represented by core plugs, with recovery efficiency used as the main evaluation parameter. Flooding tests were conducted at 65°C, 75°C, 85°C, 95°C, and 105°C, representing reservoir temperatures of selected oil wells in the Upper Assam Basin. Initial water flooding was performed using low-salinity injection water of 897 ppm, followed by subsequent flooding using higher-salinity brine of 8000 ppm under the same temperature conditions. SARA analysis was also conducted to characterize the crude oil composition in terms of saturates, aromatics, resins, and asphaltenes. The results show that low-salinity flooding at 897 ppm produced oil recovery efficiencies of 51.47%, 44.21%, 89.89%, 36.33%, and 16.22% at 65°C, 75°C, 85°C, 95°C, and 105°C, respectively. When salinity was increased to 8000 ppm, the corresponding recovery efficiencies were 22.22%, 38.73%, 59.48%, 43.33%, and 4.98%. The highest oil recovery was achieved at 85°C for both salinity levels, with 89.89% recovery at 897 ppm and 59.48% at 8000 ppm. These findings indicate that reservoir temperature strongly affects crude oil recovery, while injection brine salinity also plays an important role. The study concludes that thermal and salinity-induced wettability alteration occurs during low-salinity water flooding, contributing to improved oil recovery in brown oilfields.Downloads
References
Alnoush, W., Sayed, A., and Alyafei, N. (2019). Optimization of contact angle and interfacial tension measurements for fluid/rock systems at ambient conditions. MethodsX, 6(March), 1706–1715.
Muggeridge, A., Cockin, A., Webb, K., Frampton, H., Collins, I., Moulds, T., and Salino, P. (2014). Recovery rates, enhanced oil recovery and technological limits. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, 372(2006).
Gbadamosi, A., Patil, S., Al Shehri, D., Kamal, M. S., Hussain, S. M. S., Al-Shalabi, E. W., and Hassan, A. M. (2022). Recent advances on the application of low salinity waterflooding and chemical enhanced oil recovery. Energy Reports, 8, 9969–9996.
Li, S., Braun, O., Lauber, L., Leblanc, T., Su, X., and Feng, Y. (2021). Enhancing oil recovery from high–temperature and high–salinity reservoirs with smart thermoviscosifying polymers: A laboratory study. Fuel, 288, 119777.
Ngouangna, E. N., Jaafar, M. Z., Norddin, M., Agi, A., Yakasai, F., Oseh, J. O., Mamah, S. C., Yahya, M. N., and Al-Ani, M. (2023). Effect of Salinity on Hydroxyapatite Nanoparticles Flooding in Enhanced Oil Recovery: A Mechanistic Study. ACS Omega, 8(20), 17819–17833.
Eltoum, H., Yang, Y. L., and Hou, J. R. (2021). The effect of nanoparticles on reservoir wettability alteration: a critical review. Petroleum Science, 18(1), 136–153.
Agi, A., Junin, R., and Gbadamosi, A. (2018). Mechanism governing nanoparticle flow behaviour in porous media: insight for enhanced oil recovery applications. International Nano Letters, 8(2), 49–77.
Gbadamosi, A. O., Junin, R., Manan, M. A., Agi, A., and Yusuff, A. S. (2019). An overview of chemical enhanced oil recovery: recent advances and prospects. International Nano Letters, 9(3), 171-202.
Sagbana, P. I., Sarkodie, K., and Nkrumah, W. A. (2023). A critical review of carbonate reservoir wettability modification during low salinity waterflooding. Petroleum, 9(3), 317–330.
Neog, D. (2023). Sensitivity analysis for enhancing crude oil recovery with continuous flow gas lift: A study in reference to the porous media of the upper Assam basin, India. Heliyon, 9(7), e17466.
Qin, Y., Wu, Y., Liu, P., Zhao, F., and Yuan, Z. (2018). Experimental studies on effects of temperature on oil and water relative permeability in heavy-oil reservoirs. Scientific Reports, 8(1), 1–9.
Saadat, M., Vikse, N. B., Øye, G., and Dudek, M. (2021). A microfluidic study of oil displacement in porous media at elevated temperature and pressure. Scientific Reports, 11(1), 1–12.
Ratanpara, A., and Kim, M. (2023). Wettability alteration mechanisms in enhanced oil recovery with surfactants and nanofluids: A review with microfluidic applications. Energies, 16(24), 8003.
Rohilla, N., Katiyar, A., Rozowski, P. M., Gentilucci, A., Patil, P. D., Pal, M., and Saxena, P. (2020). Field trial for wettability alteration using surfactants: Formulation development in laboratory to the implementation and production monitoring in an offshore reservoir. Proceedings - SPE Symposium on Improved Oil Recovery, 2020, D021S053R001.
Yan, L., Golestan, M. H., Zhou, W., Hassanizadeh, S. M., Berg, C. F., and Raoof, A. (2023). Direct Evidence of Salinity Difference Effect on Water Transport in Oil: Pore-Scale Mechanisms. Energy and Fuels, 37(20), 15537–15552.
Alhammadi, A. M., Alratrout, A., Singh, K., Bijeljic, B., and Blunt, M. J. (2017). In situ characterization of mixed-wettability in a reservoir rock at subsurface conditions. Scientific Reports, 7(1), 1–9.
Tang, G. Q., and Kovscek, A. R. (2004). An experimental investigation of the effect of temperature on recovery of heavy oil from diatomite. SPE Journal, 9(02), 163-179.
Xu, S., Wang, J., Wu, J., Liu, Q., Sun, C., and Bai, B. (2018). Oil contact angles in a water-decane-silicon dioxide system: Effects of surface charge. Nanoscale Research Letters, 13(1), 108.
Fernø, M. A., Haugen, Å., and Graue, A. (2011). Wettability effects on the matrix–fracture fluid transfer in fractured carbonate rocks. Journal of Petroleum Science and Engineering, 77(1), 146-153.
Karimova, M., Kashiri, R., Pourafshary, P., and Hazlett, R. (2023). A Review of Wettability Alteration by Spontaneous Imbibition Using Low-Salinity Water in Naturally Fractured Reservoirs. Energies, 16(5), 2373.
Kathel, P., and Mohanty, K. K. (2013). Wettability alteration in a tight oil reservoir. Energy and Fuels, 27(11), 6460–6468.
Abolhasanzadeh, A., Khaz’Ali, A. R., Hashemi, R., and Jazini, M. (2020). Experimental study of microbial enhanced oil recovery in oil-wet fractured porous media. Oil and Gas Science and Technology, 75, 73.
Al-Ameer, M. A., Azad, M. S., Al-Shehri, D., Mahmoud, M., Kamal, M. S., and Patil, S. (2023). A Guide for Selection of Aging Time and Temperature for Wettability Alteration in Various Rock-Oil Systems. ACS Omega, 8(34), 30790–30801.
Francisca, F. M., Rinaldi, V. A., and Santamarina, J. C. (2003). Instability of Hydrocarbon Films over Mineral Surfaces: Microscale Experimental Studies. Journal of Environmental Engineering, 129(12), 1120–1128.
Hamouda, A., and Karoussi, O. (2008). Effect of Temperature, Wettability and Relative Permeability on Oil Recovery from Oil-wet Chalk. Energies, 1(1), 19–34.
Strand, S., Puntervold, T., and Austad, T. (2008). Effect of temperature on enhanced oil recovery from mixed-wet chalk cores by spontaneous imbibition and forced displacement using seawater. Energy and Fuels, 22(5), 3222–3225.
Yao, Y., Wei, M., and Kang, W. (2021). A review of wettability alteration using surfactants in carbonate reservoirs. Advances in Colloid and Interface Science, 294, 102477.
Shadizadeh, S. R., and Amirpour, M. (2023). Reservoir rock wettability alteration using different types of surfactants: Experimental assessment. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 45(1), 383–389.
Mohammed, M. A., and Babadagli, T. (2016). Experimental investigation of wettability alteration in oil-wet reservoirs containing heavy oil. SPE Reservoir Evaluation and Engineering, 19(4), 633–644.
Yaghi, B. M., and Al-Bemani, A. (2002). Heavy crude oil viscosity reduction for pipeline transportation. Energy Sources, 24(2), 93–102.
Sakthivel, S. (2021). Wettability Alteration of Carbonate Reservoirs Using Imidazolium-Based Ionic Liquids. ACS Omega, 6(45), 30315–30326.
Mohammed, M., and Babadagli, T. (2015). Wettability alteration: A comprehensive review of materials/methods and testing the selected ones on heavy-oil containing oil-wet systems. Advances in Colloid and Interface Science, 220, 54–77.
Lopez, G. M. C., Myers, M. B., Xie, Q., Wood, C. D., Al-Bayati, D., and Saeedi, A. (2023). Wettability Alteration to Reduce Water Blockage in Low-Permeability Sandstone Reservoirs. Transport in Porous Media, 147(2), 401–428.
Ashoori, S., Sharifi, M., Masoumi, M., and Mohammad Salehi, M. (2017). The relationship between SARA fractions and crude oil stability. Egyptian Journal of Petroleum, 26(1), 209–213.
Esmaeili, S., Sarma, H., Harding, T., and Maini, B. (2019). Review of the effect of temperature on oil-water relative permeability in porous rocks of oil reservoirs. Fuel, 237, 91–116.
Neog, D., and Borgohain, P. (2022). Effect of temperature on sandstone rock wettability behaviour: a study on the Barail sandstone outcrop of the Upper Assam Basin. Arabian Journal of Geosciences, 15(2), 1–18.
Neog, D. (2022). Effect of temperature on the pH of water flood effluents and irreducible water saturation: A study with reference to the Barail sandstone outcrop of the upper Assam Basin. Journal of Petroleum Exploration and Production Technology, 12(4), 1129-1145.
Zhang, L. ie-hu., Tong, J., Xiong, Y., and Zhao, Y. long. (2017). Effect of temperature on the oil–water relative permeability for sandstone reservoirs. International Journal of Heat and Mass Transfer, 105, 535–548.
Fassi-Fihri, O., Robin, M., and Rosenberg, E. (1991). Wettability studies at the pore level. A new approach by the use of Cryo-Scanning Electron Microscopy. Proceedings - SPE Annual Technical Conference and Exhibition, 1991, 97–110.
Piñerez Torrijos, I.D., Puntervold, T., Strand, S., Austad, T., Abdullah, H. I., and Olsen, K. (2016). Experimental Study of the Response Time of the Low-Salinity Enhanced Oil Recovery Effect during Secondary and Tertiary Low-Salinity Waterflooding. Energy and Fuels, 30(6), 4733–4739.
Barclay, S. A., and Worden, R. H. (2000). Effects of Reservoir Wettability on Quartz Cementation in Oil Fields. Quartz Cementation in Sandstones, 29, 103–117.
Dong, Y., Cao, S., Cheng, X., Liu, J., and Cao, H. (2019). Grain-size reduction of feldspar and flow of deformed granites within the Gaoligong shear zone, southwestern Yunnan, China. Science China Earth Sciences, 62(9), 1379–1398.
Dyck, B., Waters, D. J., St‐Onge, M. R., and Searle, M. P. (2019). Muscovite dehydration melting: Reaction mechanisms, microstructures, and implications for anatexis. Journal of Metamorphic Geology, 38(1), 29–52.
Lorenz, B., Ceccato, M., Andersson, M. P., Dobberschütz, S., Rodriguez-Blanco, J. D., Dalby, K. N., Hassenkam, T., and Stipp, S. L. S. (2017). Salinity-Dependent Adhesion Response Properties of Aluminosilicate (K-Feldspar) Surfaces. Energy andamp; Fuels, 31(5), 4670–4680.
Wirth, R., Kruhl, J. H., Morales, L. F. G., and Schreiber, A. (2021). Partially open grain and phase boundaries as fluid pathways in metamorphic and magmatic rocks. Journal of Metamorphic Geology, 40(1), 67–85.
Mohammed, I., Al Shehri, D., Mahmoud, M., Kamal, M. S., and Alade, O. S. (2021). Impact of Iron Minerals in Promoting Wettability Alterationsin Reservoir Formations. ACS Omega, 6(5), 4022–4033.
El-Din Mahmoud, M. A. (2018). Effect of Chlorite Clay-Mineral Dissolution on the Improved Oil Recovery from Sandstone Rocks During Diethylenetriaminepentaacetic Acid Chelating-Agent Flooding. SPE Journal, 23(05), 1880–1898.
Kamal, M. S., Mahmoud, M., Hanfi, M., Elkatatny, S., and Hussein, I. (2018). Clay minerals damage quantification in sandstone rocks using core flooding and NMR. Journal of Petroleum Exploration and Production Technology, 9(1), 593–603.
Kafili Kasmaei, A., and Rao, D. N. N. (2015). Is Wettability Alteration the Main Cause for Enhanced Recovery in Low-Salinity Waterflooding? SPE Reservoir Evaluation andamp; Engineering, 18(02), 228–235.
Al-Saedi, H. N., Flori, R. E., and Al-Jaberi, S. K. (2018). Eliminate the role of clay in sandstone: EOR low salinity water flooding. Journal of Petroleum Exploration and Production Technology, 9(2), 1475–1483.
Nasralla, R. A., Bataweel, M. A., and Nasr-El-Din, H. A. (2013). Investigation of Wettability Alteration and Oil-Recovery Improvement by Low-Salinity Water in Sandstone Rock. Journal of Canadian Petroleum Technology, 52(02), 144–154.
Xie, Y., Khishvand, M., and Piri, M. (2020). Impact of Connate Brine Chemistry on In Situ Wettability and Oil Recovery: Pore-Scale Experimental Investigation. Energy andamp; Fuels, 34(4), 4031–4045.
Shabaninejad, M., Middleton, J., Latham, S., and Fogden, A. (2017). Pore-Scale Analysis of Residual Oil in a Reservoir Sandstone and Its Dependence on Water Flood Salinity, Oil Composition, and Local Mineralogy. Energy andamp; Fuels, 31(12), 13221–13232.
Al‐Menhali, A., Niu, B., and Krevor, S. (2015). Capillarity and wetting of carbon dioxide and brine during drainage in Berea sandstone at reservoir conditions. Water Resources Research, 51(10), 7895–7914.
Piñerez Torrijos, Iván D., Puntervold, T., Strand, S., Austad, T., Tran, V. V., and Olsen, K. (2017). Impact of temperature on the low salinity EOR effect for sandstone cores containing reactive plagioclase. Journal of Petroleum Science and Engineering, 156, 102–109.
Downloads
Published
Issue
Section
License

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
